Skip to main content
SpringerLink
Log in

Acylamides of C-germylcarboxylic acids. Crystal and molecular structure of N-acetyl-N-methyl-3-(trichlorogermyl)propionamide

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The first representatives of a new class of organogermanium compounds, the acylamides of C-germylcarboxylic acids, N-acetyl-N-methyl-3-(trichlorogermyl)propionamide and N-3-(trichlorogermyl)propionylurethane, were synthesized. An X-ray structural study of Cl3GeCH2CH2C(O)NMeC(O)Me revealed a greater Ge...O intramolecular distance than that reported earlier for 3-(trichlorogermyl)propionamides. The Ge atom configuration is somewhat distorted towards a trigonal bipyramid.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. F. Mironov and A. K. Nuridzhanyan,Metalloorg. Khim., 1990,3, 1375 [Organometal.Chem., 1990,3 (Engl. Transl.)].

    Google Scholar 

  2. S. N. Gurkova, A. I. Gusev, and N. V. Alekseev,Dokl. Akad. Nauk SSSR, 1982,266, 1399 [Dokl. Chem., 1982,266 (Engl. Transl.)].

    Google Scholar 

  3. S. N. Tandura, S. N. Gurkova, and A. I. Gusev,Zh. Strukt. Khim., 1985,26, 136 [J. Struct. Chem., 1985,26 (Engl. Transl.)].

    Google Scholar 

  4. S. N. Gurkova, A. I. Gusev, and N. V. Alekseev,Zh. Strukt. Khim., 1984,25, 170 [J.Struct.Chem., 1984,25 (Engl. Transl.)].

    Google Scholar 

  5. S. N. Tandura, S. N. Gurkova and A. I. Gusev,Stroenie Biologicheski Aktivnykh Soedinenii Germaniya s Rasshirennoi Koordinatsyonnoi Sferoi, Ser. Elementoorganicheskie Soedineniya i Ikh Primenenie (The Structure of Biologically Active Germanium Compounds with Extended Coordination Sphere, Ser. Organoelement Compounds and Their Application), NIITEKhIM, Moscow, 1983 (in Russian).

    Google Scholar 

  6. T. K. Gar, N. A. Viktorov, and V. F. Mironov,Zh. Obshch. Khim., 1982,52, 1593 [J. Gen. Chem., 1982,52 (Engl. Transl.)].

    Google Scholar 

  7. G. M. Apal'kova, A. I. Gusev, S. N. Gurkova, and A. E. Feoktistov,Metalloorg. Khim., 1988,1, 942 [Organomet. Chem., 1988,1 (Engl. Transl.)].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123, Moscow, Russian Federation

    A. K. Nuridzhanyan, S. N. Gurkova, A. I. Gusev & V. F. Mironov

Authors
  1. A. K. Nuridzhanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. N. Gurkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Gusev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. F. Mironov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 762–764, April, 1993.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nuridzhanyan, A.K., Gurkova, S.N., Gusev, A.I. et al. Acylamides of C-germylcarboxylic acids. Crystal and molecular structure of N-acetyl-N-methyl-3-(trichlorogermyl)propionamide. Russ Chem Bull 42, 729–731 (1993). https://doi.org/10.1007/BF00704014

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00704014

Key words

Search

Navigation