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Synthesis of 3-substituted 4-imino-4,5-dihydro-1,2,3-triazole 1-oxides and 4-amino-1,2,3-triazole 1-oxides. Crystal and molecular structure of 4-imino-5,5-dimethyl-3-phenyl-4,5-dihydro-1,2,3-triazole 1-oxide

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

A new procedure for the synthesis of triazole N-oxides, based on base-induced intramolecular cyclization of 1-(α-cyanoalkyl)-3-aryl(hetaryl)triazen-1-oxides, is proposed. An X-ray study of 4-imino-5,5-dimethyl-3-phenyl-4,5-dihydro-1,2,3-triazole 1-oxide was carried out.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    S. G. Zlotin, O. V. Prokshits, M. O. Dekaprilevich & O. A. Lukyanov

  2. A. N. Nesmeyanov Institute of Organoelemenl Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    D. S. Yufit & Yu. T. Struchkov

Authors
  1. S. G. Zlotin
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  2. O. V. Prokshits
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  3. M. O. Dekaprilevich
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  4. D. S. Yufit
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  5. O. A. Lukyanov
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  6. Yu. T. Struchkov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 746–751, April, 1993.

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Zlotin, S.G., Prokshits, O.V., Dekaprilevich, M.O. et al. Synthesis of 3-substituted 4-imino-4,5-dihydro-1,2,3-triazole 1-oxides and 4-amino-1,2,3-triazole 1-oxides. Crystal and molecular structure of 4-imino-5,5-dimethyl-3-phenyl-4,5-dihydro-1,2,3-triazole 1-oxide. Russ Chem Bull 42, 711–717 (1993). https://doi.org/10.1007/BF00704010

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  • DOI: https://doi.org/10.1007/BF00704010

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