Abstract
A model is proposed to describe the structure of large silicon clusters. The model is illustrated for the 60-atom cluster. A structure consisting of stacked, naphthalene-like planes is investigated. Computational evidence is given in support of this hypothesis, and it is shown to be consistent with experimental photofragmentation results.
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Y. Liu, Q.-L. Zhang, F. K. Tittle, R. F. Curl, and R. E. Smalley (1986).J. Chem. Phys. 85, 7434.
Q.-L. Zhang, Y. Liu, R. F. Curl, F. K. Tittel, and R. E. Smalley (1988).J. Chem. Phys. 88, 1670.
J. L. Elkind, J. M. Alford, F. D. Weiss, R. T. Laaksonen, and R. E. Smalley (1987).J. Chem. Phys. 87, 2397.
L. A. Bloomfield, R. R. Freeman, and W. L. Brown (1985).Phys. Rev. Lett. 54, 2246.
M. F. Jarrold, J. E. Bower, and K. Creegan (1989).J. Chem. Phys. 90, 3615.
M. F. Jarrold and J. E. Bower (1988).J. Phys. Chem. 92, 5702.
D. Tománek and M. A. Schlüter (1987).Phys. Rev. B 36, 1208; (1986).Phys. Rev. Lett. 56, 1055.
K. Raghavachari and V. Logovinsky (1985).Phys. Rev. Lett. 55, 2853.
H. Kupka and K. Jug (1989).Chem. Phys. 130, 23.
J. C. Phillips (1985).J. Chem. Phys. 83, 3330.
J. R. Chelikowsky, J. C. Phillips, M. Kamal, and M. Strauss (1989).Phys. Rev. Lett. 62, 292.
J. R. Chelikowsky and J. C. Phillips (1989).Phys. Rev. Lett. 63, 1653.
P. Ballone, W. Andrconi, R. Car, and M. Parrinello (1988).Phys. Rev. Lett. 60, 271.
J. C. Phillips (1988).J. Chem. Phys. 88, 2090.
D. A. Jelski, Z. C. Wu, and T. F. George (1988).Chem. Phys. Lett. 150, 447.
D. J. Chadi (1984).Phys. Rev. B 29, 785.
S. P. McGlynn, L. G. Vanquickenborne, M. Kinoshita, and D. G. Carroll,Introduction to Applied Quantum Chemistry (Holt, Rinehart and Winston, New York, 1972), pp. 44–47.
R. S. Mulliken, C. A. Rieke, D. Orloff, and H. Orloff (1949).J. Chem. Phys. 17, 1248.
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Jelski, D.A., Wu, Z.C. & George, T.F. An inquiry into the structure of the Si60 cluster: Analysis of fragmentation data. J Clust Sci 1, 143–154 (1990). https://doi.org/10.1007/BF00703590
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DOI: https://doi.org/10.1007/BF00703590