Russian Chemical Bulletin

, Volume 43, Issue 10, pp 1676–1679 | Cite as

Spectroscopic investigation of 2-nitrodiazenoxides

  • K. I. Rezchikova
  • V. A. Shlyapochnikov
  • V. A. Tartakovsky
Physical Chemistry


2-Nitrodiazenoxides have been studied by vibrational spectroscopy methods. The main regularities of the changes in the stretching vibration frequencies of the nitro and diazenoxide groups were studied as functions of different factors.

Key words

2-nitrodiazenoxides vibrational spectra characteristic frequencies band intensity 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    J. N. Brough, B. Lythgol, and P. Naterhouse,J. Chem. Soc., 1954, 4069; J. L. Swigert and K. G. Taylor,J. Am. Chem. Soc., 1971,93, 7337; K. G. Taylor, S. R. Isaac, and J. L. Swigert,J. Org. Chem., 1972,41, 1146; R. A. Moss, M. J. Landon, K. M. Luchter, and A. Mamantov,J. Am. Chem. Soc., 1972,94, 4392; K. G. Taylor, M.-Sh. Chi, and M. S. Clark,J. Org. Chem., 1976,41, 1131; R. C. Zawalski and P. Kovacic,J. Org. Chem., 1979,144, 2130.Google Scholar
  2. 2.
    B. N. Yandovskii, B. V. Gidaspov, I. V. Tselinskii, and V. S. Kuznetsov,Zh. Org. Khim., 1987,23, 10 [J. Org. Chem. USSR, 1987,23 (Engl. Transl.)].Google Scholar
  3. 3.
    S. F. Reed,J. Org. Chem., 1967,32, 3869; A. V. Fokin, V. I. Zimin, Yu. N. Studnev, and V. F. Korotkov,Zh. Org. Khim., 1970,6, 880 [J. Org. Chem. USSR, 19706 (Engl. Transl.)].Google Scholar
  4. 4.
    I. K. Korobeinikova, O. M. Fugaeva, and G. G. Furin,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 1537 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986,35, 1391 (Engl. Transl.)].Google Scholar
  5. 5.
    A. Kuwae and K. Machida,Spectrochim. Acta, 1978,35A, 27.Google Scholar
  6. 6.
    H. B. Schlegel, S. Wolfe, and F. J. Bernardi,J. Chem. Phys., 1977,67, 4181.Google Scholar
  7. 7.
    J. D. Laposa,Spectrochim. Acta, 1979,35A, 65.Google Scholar
  8. 8.
    V. Nelson, A. Serianz, and P. Kovacic,J. Org. Chem., 1976,41, 1751.Google Scholar
  9. 9.
    V. G. Avakyan, Ph. D. Chem. Thesis, Moscow, 1971 (in Russian).Google Scholar
  10. 10.
    H. G. O. Becker,Seinfurung in die Electronentheorie Organisch-chemischer Reaktionen, VEB Deutcher Verlag der Wissenschaften, Berlin, 1974 (Russ. Transl.).Google Scholar
  11. 11.
    A. Lee Smith,Applied Infrared Spectroscopy. Fundamentals Techniques, and Analytical Problem-solving, Wiley and Sons, New York-Chichester, 1979 (Russ. Transl.).Google Scholar
  12. 12.
    L. J. Bellamy,Advances in Infrared Group Frequencies, Methuer and Co. Ltd., Burgay, Suffole, 1968 (Russ. Transl.).Google Scholar
  13. 13.
    L. V. Vilkov, V. S. Mastryukov, and N. I. Sadova,Opredelenie geometricheskogo stroeniya svobodnykh molecul [Determination of the Geometrie Structure of Free Molecules], Khimiya, Leningrad, 1978 (in Russian).Google Scholar
  14. 14.
    T. B. Brill and V. Oyumi,J. Phys. Chem., 1986,90, 2679.Google Scholar
  15. 15.
    V. P. Novikov and A. I. Malyshev,Zh. Prikl. Spektrosk., [J. Appl. Spectrosc.], 1960,33, 545 (in Russian).Google Scholar
  16. 16.
    J. S. Binkley, R. A. Whitside, P. C. Hariharan, N. Seiger, J. S. Pople, W. J. Hehre, and N. D. Nenton,GAUSSIAN-76, QCPE No 368, Indiana University, Bloomington, 1976.Google Scholar

Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • K. I. Rezchikova
    • 1
  • V. A. Shlyapochnikov
    • 1
  • V. A. Tartakovsky
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations