Abstract
A whole complex of phenomena occurring upon crystallization of substances from solutions and vapors has been considered. A generalized conception of crystallization has been developed. According to this conception the kinetics of the process and the properties of the crystallization product are determined not only by nucleation and molecular growth of crystals, but also by their directed aggregation. The role of the thermal and hydrodynamic selection of regular shaped aggregates in the course of their transformation into pseudo single crystals has been discussed. A relation between the properties of the crystals and their reactivity has been found.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1710–1717, October, 1994.
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Melikhov, I.V. Elementary acts of crystallization in an environment with high supersaturation. Russ Chem Bull 43, 1613–1621 (1994). https://doi.org/10.1007/BF00703472
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DOI: https://doi.org/10.1007/BF00703472