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Journal of Cluster Science

, Volume 3, Issue 4, pp 459–467 | Cite as

Some relationships between metal cluster chemistry and heterogeneous catalysis

  • D. F. Shriver
Proceedings Of The US-Italy International Conference On Organic Chemistry At Clusters And Surfaces, Piemonte, Italy (July 26–31, 1992)—Part II Of III

Abstract

Some analogies between organometallic chemistry and surface chemistry are developed. Comparison of Lewis acid promoted CO insertion and Zn2+ promotion of oxygenates in the hydroformylation of C2H4 over Rh, suggests that Zn2+ interaction with Rh-CO may promote migratory insertion which favors hydroformylation over hydrogenation of alkenes. CCO, which is observed in metal clusters should be a viable surface species. Finally, parallels can be found between the positioning of oxygen in clusters and on surfaces.

Key words

Metal clusters heterogeneous catalysis organometallics oxide sulfide acetylide 

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Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • D. F. Shriver
    • 1
  1. 1.Department of ChemistryNorthwestern UniversityEvanston

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