Abstract
The results of competitive and relative rate studies for various silicon hydrides and vinylmethylsiloxane compounds are presented. For example, the competitive reaction of bis(trimethylsiloxy)methylsilane with vinylpentamethyldisiloxane (A) and divinyltetramethyldisiloxane (B) show that B reacts preferentially; however, the relative rate of reaction is greater for A than B. Mechanistic aspects of hydrosilylation are also discussed.
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This paper is from the Second International Topical Workshop, “Advances in Silicon-Based Polymer Science.”
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Stein, J., Lewis, L.N., Smith, K.A. et al. Mechanistic studies of platinum-catalyzed hydrosilylation. J Inorg Organomet Polym 1, 325–334 (1991). https://doi.org/10.1007/BF00702496
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DOI: https://doi.org/10.1007/BF00702496