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Russian Chemical Bulletin

, Volume 44, Issue 3, pp 406–409 | Cite as

Synthesis of dialkoxy- and alkoxy-amino-disubstituted derivatives of B12H122−

  • B. Brellochs
  • A. Semioshkin
General and Inorganic Chemistry

Abstract

Dichloromethoxymethane reacts with the sodium salt ofcloso-dodecahydrododecaborate Na2B12H12 to give disubstituted cluster, which readily decomposes when treated with various reagents. This cluster reacts with water, forming the previously described 1,7-B12H10(OH)22−reaction with alcohols results in a novel 1,7-dialkoxy derivative, whereas interaction with morpholine in acetone solution affords the novel anion, 1-O-I-Pri-7-O(CH2CH2)N-B12H102−. All of these derivatives were isolated as cesium salts and characterized by one- and two-dimensional NMR techniques.

Keywords

closo-dodecahydrododecaborate dichloromethoxymethane 1,7-dialkoxy derivatives 1-isopropoxy-7-morpholino-closo-decahydrododecaborate NMR-spectra 

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References

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    B. Brellochs and A. Semioshkin,J. Chem. Soc. Dalton. Trans., 1995,in press. Google Scholar
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    A. Semioshkin,Ph. D. Thesis (Chem), München, BRD, 1994, 51p.Google Scholar
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    J. March,Advanced Organic Chemistry, 3rd edition, John Wiley & Sons, New York, 1985.Google Scholar
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    B. Brellochs and A. SemioshkinJ. Chem. Soc. Dalton. Trans., 1995, in pressGoogle Scholar
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    H. O. Kalinowski, S. Berger, and S. Brown,13 C NMR-Spectroscopy, Georg Thieme Verlag, Stuttgart-New York, 1984, 288.Google Scholar

Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • B. Brellochs
    • 1
  • A. Semioshkin
    • 2
  1. 1.Institute of Inorganic Chemistry of Munich UniversityMunichGermany
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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