Russian Chemical Bulletin

, Volume 44, Issue 2, pp 280–286 | Cite as

Charge control of the complex formation of phenol with unsaturated compounds containing organoelement substituents from group IV

8. Furan derivatives
  • A. N. Egorochkin
  • S. E. Skobeleva
  • T. G. Mushtina
Physical Chemistry


The frequency shifts (Δv (OH)) of phenol and the resonance components (δvr) of these shifts in the IR spectra of forty H-complexes of phenol with furan derivatives containing organic, organosilicon, organogermanium, and organotin substituents are studied. The values of Δv and ΔvR are linearly related to quantum chemical parameters of the variation of the effective charges of the furan ring atoms affected by σ- and π-interactions with organic substituents. The effect of the conjugation between an organoelement substituent and the furan ring on the effective charges is estimated. The resonance parameters (σR) of organoelement substituents in derivatives of benzene, thiophene, and furan and the reasons for the non-versatility of σR are considered.

Key words

furan derivatives H-complexes charge control of complex formation effective charge non-versatility of resonance parameters 


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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • A. N. Egorochkin
    • 1
  • S. E. Skobeleva
    • 1
  • T. G. Mushtina
    • 1
  1. 1.Institute of Organometallic ChemistryRussian Academy of SciencesNizhnii NovgorodRussian Federation

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