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Journal of Inorganic and Organometallic Polymers

, Volume 2, Issue 4, pp 373–386 | Cite as

Polymers containing metal chelate units. I. Immobilized mono- and binuclear chelates of nickel(II) and cobalt(II)

  • I. E. Uflyand
  • A. D. Pomogailo
Article

Abstract

A number of polymer carriers with chelating groups such as diketones, diacylamines, and enaminoketones has been synthesized. The immobilized mono- and binuclear chelates have been prepared by the interaction of these polymeric ligands with nickel(II) and cobalt(II) acetates in alcohol. Spectral and magnetic data confirm the tetrahedral structure of the cobalt complexes and octahedral structure of the nickel complexes. The catalytic properties of the immobilized complexes in ethylene dimerization and butadiene polymerization have been investigated.

Key words

Polymeric ligands macromolecular metal complexes nickel chelates cobalt chelates ethylene dimerization butadiene polymerization 

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Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • I. E. Uflyand
    • 1
  • A. D. Pomogailo
    • 2
  1. 1.Department of ChemistryState Pedagogical InstituteRostov-on-DonUSSR
  2. 2.Institute of Chemical PhysicsAcademy of Sciences, Chernogolovka Moscow RegionUSSR

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