Abstract
Phosphazene-substituted polysiloxanes have been synthesized via a hydrosilylation reaction of allyl derivatives of cyclophosphazenes with polymethylhydrosiloxanes. It turned out that a proper choice of both the spacer between the phosphazene group and the double bond and the position of the phosphazene group at the spacer is important for the preparation of soluble polysiloxanes with a high content of phosphazene units.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. Noshay and J. E. McGrath,Block Copolymers (Academic Press, New York, 1977).
W. Noll,The Chemistry and Technology of Silicones (Academic Press, New York, 1968).
J. L. Speier,Adv. Organomet. Chem. 17, 407 (1979).
M. S. K. Lee, G. W. Gray, D. Lacey, and K. J. Toyne,Makromol. Chem. Rapid Commun. 10, 325 (1989).
H. R. Allcock, W. D. Coggio, R. S. Archibald, and D. J. Brennan,Macromolecules 22, 3571 (1989).
P. Wisian-Neilson and M. S. Islam,Macromolecules 22, 2026 (1989).
K. Ramachandran and C. W. Allen,Inorg. Chem. 22, 1445 (1983).
A. L. Smith,Chemical Analysis of Silicones (Wiley, New York, 1974).
C. W. Allen, inInorganic and Organometallic Polymers, ACS Symposium Series No. 360, M. Zeldin, K. J. Wynne, and H. R. Allcock, eds. (American Chemical Society, Washington, D.C., 1988), p. 290.
R. Spindler and D. F. Shriver,Macromolecules 21, 648 (1988).
G. de Marignan, D. Teyssié, S. Boileau, J. Malthête, and C. Noël,Polymer 29, 1318 (1988).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Puyenbroek, R., Jekel, A.P. & van de Grampel, J.C. Synthesis of phosphazene-substituted polysiloxanes. J Inorg Organomet Polym 1, 105–114 (1991). https://doi.org/10.1007/BF00701032
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00701032