Abstract
The title compounds were prepared and X-ray analysis was performed (R = 0.064 and 0.035 for 1309 and 1637 reflections, respectively). In the former the intramolecular S→Si coordination interactions are absent and the Si atom has undistorted tetrahedral coordination with an S...Si distance of 4.034 Å. Crystals of the latter are built of centrosymmetric dimeric H-complexes (S...H(N) 2.58 Å, the S...HN angle 168°).
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Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 198–202, January, 1993.
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Mozzhukhin, A.O., Ovchinnikov, Y.E., Antipin, M.Y. et al. Crystal and molecular structure of 1-(trimethylsilylmethyl)hexahydroazepine-2-thione and hexahydroazepine-2-thione. Russ Chem Bull 42, 181–184 (1993). https://doi.org/10.1007/BF00700005
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DOI: https://doi.org/10.1007/BF00700005