Skip to main content
SpringerLink
Log in

Crystal structure of the La3+ sandwich complex based on 8-membered macrocyclic siloxanolate ligands

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The product of the reaction between anhydrous lanthanum trichloride and potassium vinylsiloxanolate, K5[VinSiO2]8La4(μ4-OH)[O2SiVin]8 · 5n-BuOH·2H2O has been studied by X-ray diffraction. The compound is a «sandwich»-type complex where macrocyclic vinyloctasiloxanolate ligands with regularcis-configuration have co-axial and antiparallel orientation. These ligands coordinate a planar «cationic layer» formed by four La3+ ions and stabilized by an additional μ4-OH− bridge ligand. A three-dimensional cage structure of complex lanthansiloxanolate pentaanions linked through the coordinated K+ counter-ions is formed in the crystal studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O.I.Shchegolikhina, A.A.Zhdanov, V.A.Igonin, Yu.E.Ovchinnikov, V.E.Shklover, and Yu.T.Struchkov,Metalloorgan.Khimiya, 1991,4, 74 [Organomet.Chem.USSR].

    Google Scholar 

  2. M.M.Levitsky, O.I.Shchegolikhina, A.A.Zhdanov, V.A.Igonin, Yu.E.Ovchinnikov, V.E.Shklover, and Yu.T.Struchkov,J.Organometall.Chem., 1991,401, 199.

    Google Scholar 

  3. V.A.Igonin, S.V.Lindeman, K.A.Potekhin, V.E.Shklover, Yu.T.Struchkov, O.I.Shchegolikhina, A.A.Zhdanov, and I.V.Razumovskaya,Metalloorgan.Khimiya, 1991,4, 790 [Organomet. Chem. USSR].

    Google Scholar 

  4. V.A.Igonin, O.I.Shchegolikhina, S.V.Lindeman, M.M.Levitsky, Yu.T.Struchkov, and A.A.Zhdanov,J.Organometall.Chem., 1992,423, 351.

    Google Scholar 

  5. F.Libau,Strukturnaya Khimiya Silikatov, (The Structural Chemistry of Silicates), Mir, Moscow, 1988.

    Google Scholar 

  6. N.S.Zefirov and B.A.Palyulin,Dokl.Akad.Nauk SSSR, 1980,252, 11 [Dokl.Chem.].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813, Moscow, Russian Federation

    V. A. Igonin, S. V. Lindeman, Yu. T. Struchkov, O. I. Shchegolikhina, Yu. A. Molodtsova, Yu. A. Pozdnyakova & A. A. Zhdanov

Authors
  1. V. A. Igonin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Lindeman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. T. Struchkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. I. Shchegolikhina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. A. Molodtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yu. A. Pozdnyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. A. Zhdanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 184–189, January, 1993.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Igonin, V.A., Lindeman, S.V., Struchkov, Y.T. et al. Crystal structure of the La3+ sandwich complex based on 8-membered macrocyclic siloxanolate ligands. Russ Chem Bull 42, 168–173 (1993). https://doi.org/10.1007/BF00700002

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00700002

Key words

Search

Navigation