Abstract
The condensation of methyl acrylate with the title β-ketosulfide and β-ketosulfone was studied. The primary adduct of β-ketosulfone with acrolein readily undergoes intramolecular aldolization to give bicyclo[3.2.1]octane derivatives. The molecular structure of one of them was elucidated by X-ray analysis.
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Deceased Nov., 1, 1992.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 118–122, January, 1993.
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Veselovsky, V.V., Zhuzbaev, B.T., Turdybekov, K.M. et al. Michael reactions withtrans-3-isopropenyl-2-phenylthiocyclopentan-1-one andtrans-3-isopropenyl-2-phenylsulfonylcyclopentan-1-one. Russ Chem Bull 42, 106–110 (1993). https://doi.org/10.1007/BF00699987
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DOI: https://doi.org/10.1007/BF00699987