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Russian Chemical Bulletin

, Volume 42, Issue 8, pp 1431–1432 | Cite as

The axial long-range interaction in 1,4,7,10-tetraazacyclotridecanenickel(ii) bis-tetraethynilborate Ni([13]aneN4)(teb)2

  • M. A. Porai-Koshits
  • G. A. Kukina
Brief Communications
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Abstract

In Ni([13]aneN4)(teb)2 (1) axial long-range interaction with the teb anions leads to bipyramidal coordination of Ni (coordination number 4+2), whereas in 1,4,8,11-tetraazaundecanenickel bis-tetraethynilborate, [Ni(2,3,2-tet)teb]teb (2) only one of the teb anions is involved in coordination. Shortening of the equatorial Ni-N bond by 0.1 Å in1 compared with2 leads to elongation of the axial secondary bonds by about 0.6 Å.

Key words

axial long-range interaction nickel complexes tetraamines crystal chemistry 

References

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    G. A. Kukina, M. A. Porai-Koshits, G. G. Sadikov, Yu. N. Shevchenko, and A. N. Yesaulenko,Koord. Khim., 1986,12, 1279 [Sov. J. Coord. Chem., 1986,12 (Engl. Transl.)].Google Scholar
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    L. R. Furenlid, M. W. Renner, D. J. Szalda, and E. Fuita,J. Am. Chem. Soc., 1991,113, 883.Google Scholar
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    Yu. N. Shevchenko and M. A. Porai-Koshits,Zh. Obshch. Khim., 1990,60, 1342 [J. Gen. Chem. USSR, 1990,60 (Engl. Transl.)].Google Scholar

Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • M. A. Porai-Koshits
    • 1
  • G. A. Kukina
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation

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