Russian Chemical Bulletin

, Volume 42, Issue 8, pp 1313–1315 | Cite as

The adsorptivity of organic substances with various physico-chemical properties

1. Isotherms of adsorption of organic substances on carbon black
  • T. V. Baikova
  • M. L. Gubkina
  • K. M. Nikolaev
  • N. S. Polyakov
Physical Chemistry


The adsorption isotherms of benzene,n-hexane, cyclohexane, and 1,2-dibromo-1,1,2,2-tetrafluoroethane on a nonporous carbon adsorbent, carbon black, were calculated from the results of a gas-chromatographic experiment at 373 K. A general equation of adsorption isotherm for vapors of organic substances on nonporous sorbents that was proposed earlier is shown to be valid in the range of relative pressures,p/ps, of 10−7–1 and temperatures of 293–373 K.

Key words

adsorption gas chromatography carbon sorbents, carbon black molar volume adsorption isotherm 


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  1. 1.
    M. M. Dubinin and N. S. Polyakov,Izv. Akad.Nauk SSSR., Ser. Khim., 1985, 1943 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985,3, 1791 (Engl. Transl.)].Google Scholar
  2. 2.
    P. I. Babaev, M. M. Dubinin, and A. A. Isirikyan,Izy. Akad. Nauk SSSR., Ser. Khim., 1976, 1929 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1976, No. 8 (Engl. Transl.)].Google Scholar
  3. 3.
    D. A. Vyakhirev, A. F. Shushunov,Rukovodstvo po gasovoi chromatographii [Handbook on Gas Chromatography] Vyzshaya shkola, Moscow, 1975, 302 (in Russian).Google Scholar
  4. 4.
    M. V. Degtyarev, M. M. Dubinin, K. M. Nikolaev, and N. S. Polyakov,Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 1463 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989,38, 1337 (Engl. Transl.)].Google Scholar
  5. 5.
    M. M. Dubinin and E. D. Zaverina,Zh. Fiz. Khim., 1949,23, 1129 [J. Phys. Chem. USSR, 1949,23 (Engl. Transl.)].Google Scholar
  6. 6.
    M. M. Dubinin,Adsorbziya i poristost [Adsorption and Porosity], Voen. Akad. Khim. Zashchity, Moscow, 1972, 127 (in Russian).Google Scholar
  7. 7.
    Spravochnik khimika [Handbook of Chemist], Khimiya, Leningrad-Moscow, 1963,2, 1168 (in Russian).Google Scholar
  8. 8.
    Promyshlennye ftororganicheskie soedineniya. Spravochnik [Industrial Organofluorine Compounds. The Handbook], Khimiya, Leningrad, 1990,463 (in Russian).Google Scholar
  9. 9.
    F. Daniels and P. A. Alberty,Physical Chemistry, 4th Ed., J. Wiley and Sons, New York-London-Sydney-Toronto, 1975.Google Scholar

Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • T. V. Baikova
    • 1
  • M. L. Gubkina
    • 1
  • K. M. Nikolaev
    • 1
  • N. S. Polyakov
    • 1
  1. 1.Institute of Physical ChemistryRussian Academy of SciencesMoscowRussian Federation

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