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Chemihiminescence by the interaction of XeO3 and the products of photolysis of uranyl solutions in sulfuric acid

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Abstract

Using the chemiluminescence oxidation of U(IV) and H2O2 with xenon trioxide as a model, it has been found that during the photolysis of solutions of UO2SO4 in sulfuric acid in the absence of any organic compounds, the accumulation of U(SO4)2 and H2O2 takes place as a result of the reaction of the primary products of the photoreduction of uranyl ion,i.e., UO2 + and the OH radical.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    L. A. Khamidullina, S. V. Lotnik & V. P. Kazakov

Authors
  1. L. A. Khamidullina
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  2. S. V. Lotnik
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  3. V. P. Kazakov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 751–754, April, 1994.

The work was financially supported by the Russian Foundation for Basic Research, Project 93-03-12291.

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Khamidullina, L.A., Lotnik, S.V. & Kazakov, V.P. Chemihiminescence by the interaction of XeO3 and the products of photolysis of uranyl solutions in sulfuric acid. Russ Chem Bull 43, 704–707 (1994). https://doi.org/10.1007/BF00699852

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  • DOI: https://doi.org/10.1007/BF00699852

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