Abstract
The structure of 3-bromo-trans-2,6-diallyl-Δ3-piperideine hydrochloride was determined by X-ray diffraction analysis. The corresponding base was prepared by reductive diallylation of 3-bromopyridine with triallylborane. 3-Bromo-cis-2,6-diallyl-Δ3-piperideine3 was prepared by heatingtrans-isomer2 with triallylborane at 130 °C followed by deboronation of the resulting aminoborane with a solution of sodium hydroxide.
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Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 705–707, April, 1994.
This work was carried out with the financial support of the Russian Foundation for Basic Research (project No 93-03-18193).
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Bubnov, Y.N., Shagova, E.A., Evchenko, S.V. et al. Synthesis and molecular structure of 3-bromo-trans-2,6-diallyl-Δ3-piperideine hydrochloride. Russ Chem Bull 43, 657–659 (1994). https://doi.org/10.1007/BF00699843
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DOI: https://doi.org/10.1007/BF00699843