Abstract
Trimethylsilyloxy derivatives of 1,2,4-triazole, 3(5)-nitro-1,2,4-triazole, and tetrazole are inert toward 2-nitro-1-trimethylsilyloxy-2-azapropane, but they react with 1-chloro-2-nitro-2-azapropane to give the corresponding nitraminomethyl derivatives. Silyiated 1,2,4-triazole undergoes bis-nitraminomethylation to give a triazolium salt.
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References
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1666–1668, September, 1993.
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Apasov, E.T., Kalinin, A.V., Ioffe, S.L. et al. Nitraminomethylation of silylated polynitrogen heterocyclic compounds in nonaqueous solutions. Russ Chem Bull 42, 1604–1605 (1993). https://doi.org/10.1007/BF00699206
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DOI: https://doi.org/10.1007/BF00699206