Abstract
The stereoselelectivity of the reaction of mercuric acetate with dimethyl bicyclo[2.2.2]oct-2-en-5, 6-cis-endo-carboxylate in acetic acid was studied. One of the reaction products is formed when the reagent attacks the double bond from the sterically less accessible side. The nature of the orientation effect of the carboxylate groups is discussed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1646–1648, September, 1993.
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Sokolova, T.N., Kartashov, V.R., Vasil'eva, O.V. et al. Stereoselectivity of the reaction of mercuric acetate with dimethyl bicyclo[2.2.2]oct-2-en-5,6-cis-endo-dicarboxylate. Russ Chem Bull 42, 1583–1585 (1993). https://doi.org/10.1007/BF00699200
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DOI: https://doi.org/10.1007/BF00699200