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Reactions of metallated 1-hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline with electrophiles

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Abstract

Reactions of metallated 1-hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline with electrophilic reagents followed by oxidation result in mono- and bifunctional substituted nitroxides of 3-imidazoline and an imidazolidine series including enaminocarbonyl and -thiocarbonyi derivatives and enaminoimines, the spin-labeled chelating reagents.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1612–1616, September, 1993.

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Reznikov, V.A., Vishnivetskaya, L.A. & Volodarskii, L.B. Reactions of metallated 1-hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline with electrophiles. Russ Chem Bull 42, 1547–1551 (1993). https://doi.org/10.1007/BF00699192

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  • DOI: https://doi.org/10.1007/BF00699192

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