Abstract
The chemical heterogeneity of polyphenylenes obtained by trimerization poiycycio-condensation of acetylaromatic compounds has been investigated by GLC-MS analysis of the products of trimerization cyclocondensation of acetophenone. The mechanism for the formation of side products of the reaction is discussed. The presence of dypnone fragments in the polyphenylene structure results in a decrease in the thermal stability of these polymers.
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References
V. V. Korshak,Raznozvennost'polimerov [Chemical Heterogeneity of Polymers], Nauka, Moscow, 1977, 5 (in Russian).
V. V. Korshak, M. M. Teplyakov, and R. A. Dvorikova,Vysokomol. Soedin., 1982,A24, 277 [Polym. Sci. USSR, 1982,A24 (Engl. Transl.)].
Atlas of Spectral Data and Physical Constants for Organic Compounds, 2nd ed., CPC Press, Cleveland, Ohio, 1975,2, 329;Ibid, 437.
R. C. Elderfield and J. P. King,J. Am. Chem. Soc., 1954,76, 277.
B. V. Rozynov, M. M. Teplyakov, V. P. Chebotarev, and V. V. Korshak,Izv. Akad. Nauk SSSR, Ser. Khim., 1974, 1602 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1974,32, No. 7 (Engl. Transl.)].
R. W. Roeske, D. B. Bright, R. L. Johnson, W. J. DeJarlais, R. W. Bush, and H. R. Snyder,J. Am. Chem. Soc., 1960,82, 3128.
H. W. Moore and H. R. Snyder,J. Org. Chem., 1963,28, 53.
G. Hesse and M. Maurer,Ann., 1962,658, 21.
V. V. Mezheritskii and G. N. Dorofeenko,Khim. Geterotsikl. Soedin., 1971, 160 [Chem. Heterocycl. Comp. USSR, 1971 (Engl. Transl.)].
Atlas of Spectral Data and Physical Constants for Organic Compounds, 2nd ed., CPC Press, Cleveland, Ohio, 1975,4, 557.
D. L. Kursanov, Z. N. Parnes, M. I. Kalinkin, and N. M. Loim,Ionic Hydrogenation and Related Reactions.Sov. Sci. Rev. Suppl. Series., Chemistry 1, Harwood Academic Publishers, Chur-London-Paris-New York, 1985, 252 p.
A. I. Kovalev, T. N. Balykova, S. V. Lindeman, M. M. Teplyakov, I. A. Khotina, A. L. Rusanov, and Yu. T. Struchkov,Izv. Akad. Nauk, Ser. Khim., 1994, No. 5 [Russ. Chem. Bull., 1994,43, No. 5 (Engl. Transl.)].
N. P. Buu-Hoi, M. Delcey, P. Jacquignon, and F. Perin,J. Heterocycl. Chem., 1986,5, 259.
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Deceased March, 1993.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1595–1601, September, 1993.
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Kovalev, A.I., Lyakhovetskli, Y.I., Teplyakov, M.M. et al. Investigation of the chemical heterogeneity of polyphenylenes using the condensation of methyl aryl ketones as a model reaction. Russ Chem Bull 42, 1529–1535 (1993). https://doi.org/10.1007/BF00699189
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DOI: https://doi.org/10.1007/BF00699189