Abstract
The PhCH2CH2CNOs3(CO)11 complex was prepared by the reaction of Os3(CO)12 with β-cyanoethylbenzene, while the reaction with (CO)3CrPhCH2CH2CN gave a heterometallic derivative, (CO)3CrPhCH2CH2CNOs3(CO)11. A bicluster complex, Co4(CO)9PhCH2CH2CNOs3(CO)11, was synthesized for the first time by the reaction of PhCH2CH2CNOs3(CO)11 with Co2(CO)8; Co4(CO)9PhCH2CH2CN was also obtained.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 145–147, January, 1994.
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Kaganovich, V.S., Rybinskaya, M.I. A mixed Co- and Os-containingn,π-bicluster complex based on β-phenylpropionitrile. Russ Chem Bull 43, 142–144 (1994). https://doi.org/10.1007/BF00699154
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DOI: https://doi.org/10.1007/BF00699154