Abstract
The synthesis of 2-allylseleno-3,5-dicyano-6-hydroxy-4-phenylpyridine has been carried out and its cyclization into 6,8-dicyano-5-hydroxy-3-iodomethyl-7-phenyl-2,3-dihydroselenazolo[3,2-a]pyridinium triiodide has been studied. X-ray investigation shows that allylselenopyridine in the crystalline state exists as hydroxy derivative and the allyl substituent is approximately perpendicular to the heterocyclic plane. In crystal the molecules are linked by hydrogen bonds forming dimers.
Similar content being viewed by others
References
V. D. Dyachenko, Yu. A. Sharanin, V. P. Litvinov, and A. V. Turov,Ukr. Khim. Zh., 1990,56, 408.
V. D. Dyachenko, Yu. A. Sharanin, A. M. Shestopalov, L. A. Rodinovskaya, A. V. Turov, V. P. Litvinov, and V. K. Promonenkov,Zh. Obshch. Khim., 1990,60, 2384 [J. Gen. Chem. USSR, (Engl. Transl.)].
V. N. Nesterov, V. E. Shklover, Yu. T. Struchkov, Yu. A. Sharanin, and V. D. Dyachenko, Izv.Akad. Nauk SSSR, Ser. khim., 1989, 2585 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989 (Engl. Transl.)].
A. M. Shestopalov, V. N. Nesterov, Yu. A. Sharanin, V. P. Litvinov, V. Yu. Mortikov, V. E. Shklover, and Yu. T. Struchkov,Khim. Geterotsikl. Soedin., 1989, 557 [Chem. Heterocycl. Cpd. (Engl. Transl.)].
Yu. V. Zefirov,Zh. Obshch. Khim., 1976,46, 2636 [J. Gen. Chem. USSR (Engl. Transl.)].
F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. Taylor,J. Chem. Soc. Perkin Trans, II, 1987, Sl.
A. Bondi,J. Phys. Chem., 1966,70, 3006.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 122–124, January, 1994.
Rights and permissions
About this article
Cite this article
Nesterov, V.N., Dyachenko, V.D., Sharanin, Y.A. et al. Synthesis, properties, and structure of 2-allylseleno-3,5-dicyano-6-hydroxy-4-phenylpyridine. Russ Chem Bull 43, 118–120 (1994). https://doi.org/10.1007/BF00699148
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00699148