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Photochemical addition of diethyl ether to β,β,β',β'-tetrakis(trifluoromethyl)divinyl ether

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Abstract

The 1:1 adducts of diethyl and β,β,β',β'-tetrakis(trifluoromethyl)divinyl ether (1),i.e., 3,5-(ee)-bis[2,2,2-trifluoro-1-(trifluoromethyl)ethyl]-2,6-dimethyl-1,4-dioxane (2) (3 isomers) and 4-ethoxy-1,1,1-trifluoro-2-trifluoromethyl-3-[3,3,3-trifluoro-2(trifluoromethyl)propenyloxy]pentane (3), have been obtained by UV-irradiation of a solution of divinyl ether1 in diethyl ether. The X-ray structural investigation of the all-(e)-isomer of dioxane (2) has been carried out.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. Yu. Volkonsky, V. R. Polishchuk, E. M. Kagramanova, E. I. Mysov, N. E. Mysova, M. Yu. Antipin & Yu. T. Struchkov

Authors
  1. A. Yu. Volkonsky
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  2. V. R. Polishchuk
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  3. E. M. Kagramanova
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  4. E. I. Mysov
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  5. N. E. Mysova
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  6. M. Yu. Antipin
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  7. Yu. T. Struchkov
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Additional information

Deceased.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 85–88, January, 1994.

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Volkonsky, A.Y., Polishchuk, V.R., Kagramanova, E.M. et al. Photochemical addition of diethyl ether to β,β,β',β'-tetrakis(trifluoromethyl)divinyl ether. Russ Chem Bull 43, 80–83 (1994). https://doi.org/10.1007/BF00699140

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  • DOI: https://doi.org/10.1007/BF00699140

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