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Preparation and reactivity of metal-containing monomers.

36. Thermal stability of methacryloylacetonates and polymethacryloylacetonates of transition metals

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Abstract

The thermal decomposition of CuII, CoII, NiII, MnII, FeIII, and CrIII methacryloylacetonates has been compared with the thermal behavior of the corresponding acetylacetonates and poly (methacryioylacetonates). Dehydration and thermal polymerization of methacryioylacetonates occur at 110–160 °C. The results of the thermolysis conform with the Irving-Williams sequence for the stability of the complexes of bivalent transition metals. Thermal destruction of metallopolymers differs from that of low-molecular analogs. The temperature of complete decomposition of the compounds studied correlates with the number of electrons in the d-orbital of the metal.

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Authors and Affiliations

  1. Institute of Chemical Physics in Chemogolovka, Russian Academy of Sciences, 142432, Chemogolovka, Moscow Region, Russian Federation

    T. I. Movchan, N. I. Solov'eva & L. A. Petrova

  2. Institute of New Chemical Problems, Russian Academy of Sciences, 142432, Chemogolovka, Moscow Region, Russian Federation

    G. P. Belov & A. D. Pomogailo

  3. I. I. Mechnikov Odessa State University, 270000, Odessa, Ukraine

    I. S. Voloshanovskii

Authors
  1. T. I. Movchan
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  2. N. I. Solov'eva
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  3. L. A. Petrova
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  4. I. S. Voloshanovskii
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  5. G. P. Belov
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  6. A. D. Pomogailo
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Additional information

For part 35 seeRuss. Chem. Bull., 1993,42, 1972.

Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 43–47, January, 1994.

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Movchan, T.I., Solov'eva, N.I., Petrova, L.A. et al. Preparation and reactivity of metal-containing monomers.. Russ Chem Bull 43, 35–40 (1994). https://doi.org/10.1007/BF00699131

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  • DOI: https://doi.org/10.1007/BF00699131

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