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Preparation ofN, N-dialkyl methylenebisnitramines

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Abstract

The possibility of obtainingN, N'-dialkyl methylenebisnitramines from primary nitramines and formaldehyde in dilute H2SO4 (65–85%) has been shown. The reaction starting from two different nitramines results in a mixture of one asymmetrically and two symmetrically substituted products.

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References

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    V. A. Tartakovskii, A. S. Ermakov, V. A. Koroban, F. R. Alimov & N. V. Sigai

Authors
  1. V. A. Tartakovskii
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  2. A. S. Ermakov
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  3. V. A. Koroban
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  4. F. R. Alimov
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  5. N. V. Sigai
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1999–2001, November, 1993.

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Tartakovskii, V.A., Ermakov, A.S., Koroban, V.A. et al. Preparation ofN, N-dialkyl methylenebisnitramines. Russ Chem Bull 42, 1916–1918 (1993). https://doi.org/10.1007/BF00699017

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  • DOI: https://doi.org/10.1007/BF00699017

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