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Peculiarities of dissociative ionization of alkylcyclopentadienyl nitrosyl π-complexes of nickel

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Abstract

The decomposition of alkylcyclopentadienyl nitrosyl π-complexes of nickel, (C5H4R)(NO)Ni (R=H, Et,i-Pr, CH2Ph), under the action of electron impact has been studied. The nature of the nitrosyl ligand has been shown to be the factor determining the main fragmentation pathway which involves the abstraction of an NO molecule. The effect of the nature of the ligand on the ability of the molecular ion (C5H4R)LNi+ (L=C5H4R, C5H5, C3H5, NO) to rearrange with hydrogen atom migration from one ligand to another has been considered. The structure of the alkyl group R determines a competing fragmentation pathway involving cleavage of the β-C-C bond with respect to the cyclopentadienyl ring in the substituent.

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References

  1. O. N. Druzhkov, Yu. A. Andrianov, and L. M. Dyagileva,Zhurn. Obshch. Khimii, 1977,47, 1836 [J. Gen. Chem., 1977,47 (Engl. Transl.)].

    Google Scholar 

  2. Yu. A. Andrianov, O. N. Druzhkov, A. S. Smirnov, and V. A. Dodonov,Zhurn. Obshch. Khimii, 1981,51, 2508 [J. Gen. Chem., 1981,51 (Engl. Transl.)].

    Google Scholar 

  3. Yu. A. Andrianov, O. N. Druzhkov, A. S. Smirnov, R. G. Nazarova, and V. A. Dodonov,Zhurn. Obshch. Khimii, 1978,48, 1159 [J. Gen. Chem., 1978,48 (Engl. Transl.)].

    Google Scholar 

  4. Yu. A. Andrianov, O. N. Druzhkov, V. P. Mar'in, and A. S. Smirnov,Tez. Dokl. IV Vsesoyuznoi Konf. po Mass- Spectrometrii [Abstracts of Reports of the IV All-Union Confer- ence on Mass Spectrometry], Sumy, 1986, part 5, p.8 (in Russian).

  5. Yu. A. Andrianov, V. P. Mar'in, O. N. Druzhkov, and G. A. Razuvaev,Dokl. Akad. Nauk. SSSR, 1978296, 1125 [Dokl. Chem., 1978,296 (Engl. Transl.)]

    Google Scholar 

  6. J. Müller,J. Organomet. Chem., 1970,23, C38.

    Google Scholar 

  7. J. Müller,Angew. Chem., Int. Ed., 1972,11, 653.

    Google Scholar 

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Authors and Affiliations

  1. Research Institute of Nizhnii Novgorod State University, 13 ul. Surganova, Minsk

    Yu. A. Andrianov & L. G. Sedova

  2. Institute of Physical Organic Chemistry, Byelorussian Academy of Sciences, 13 ul. Surganova, 220603, Minsk

    V. L. Shirokii & V. A. Knizhnikov

Authors
  1. Yu. A. Andrianov
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  2. L. G. Sedova
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  3. V. L. Shirokii
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  4. V. A. Knizhnikov
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Additional information

Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1985–1988, November, 1993.

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Andrianov, Y.A., Sedova, L.G., Shirokii, V.L. et al. Peculiarities of dissociative ionization of alkylcyclopentadienyl nitrosyl π-complexes of nickel. Russ Chem Bull 42, 1902–1905 (1993). https://doi.org/10.1007/BF00699014

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  • DOI: https://doi.org/10.1007/BF00699014

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