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Organothallium compounds. Mechanistic study of the disproportionation reaction of organothallium compounds with copper in acetonitrile

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Abstract

Disproportionation reactions of various phenyl- and thienylthallium dicarboxylates with copper in acetonitrile have been carried out. The reaction mechanism proposed involves the participation of the ArTl2+ dication and various cationic pairs of the dication and the intermediate formation of organothallium radicals.

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References

  1. A. McKillop, J. D. Hunt, and E. C. Taylor,J. Organometal. Chem., 1970,24, 77.

    Google Scholar 

  2. E. C. Taylor, H. W. Altland, and A. McKillop,J. Org. Chem., 1975,40, 2351.

    Google Scholar 

  3. V. I. Bregadze, A. Ya. Usyatinsky, and N. N. Godovikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 1426 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981,30 (Engl. Transl.)].

    Google Scholar 

  4. H. Kurosawa and M. Yasuda,J. Chem. Soc., Chem. Commun., 1978, 716.

  5. H. Kurosawa and M. Sato,Organometallics, 1982,1, 440

    Google Scholar 

  6. I. F. Gun'kin, A. I. Idelevich, and M. N. Rahlevskaya,Zh. Obshch. Khimii, 1987,57, 1789 [J. Gen. Chem., 1987,57 (Engl. Transl.)].

    Google Scholar 

  7. I. F. Gun'kin, A. I. Idelevich, and K. P. Butin,Metalloorg. Khim., 1990,3, 602 [J. Organometal. Chem. USSR, 1990,3 (Engl. Transl.)].

    Google Scholar 

  8. I. F. Gun'kin, A. I. Idelevich, and K. P. Butin,Metalloorg. Khim., 1991,4, 384 [J. Organometal. Chem. USSR, 1991,4 (Engl. Transl.)].

    Google Scholar 

  9. G. B. Deacon and D. G. Vince,Austral. J. Chem., 1975,28, 1931.

    Google Scholar 

  10. I. F. Gun'kin, K. P. Butin, I. P. Beletskaya, and O. A. Reutov,Izv. Akad. Nauk SSSR, Ser. Khim., 1978, 1016 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1978,27, 879 (Engl. Transl.)].

    Google Scholar 

  11. I. F. Gun'kin, K. P. Butin, 1. P. Beletskaya, and O. A. Reutov,Izv. Akad. Nauk SSSR, Ser. Khim., 1978, 1297 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1978,27, 1128 (Engl. Transl.)].

    Google Scholar 

  12. I. F. Gun'kin and K. P. Butin,Metalloorg. Khim., 1989,2, 1369 [J. Organometal. Chem. USSR, 1989,2 (Engl. Transl.)].

    Google Scholar 

  13. K. P. Butin, I. F. Gun'kin, and A. I. Idelevich,Metalloorg. Khim., 1989,2, 1373 [J. Organometal. Chem. USSR, 1989,2 (Engl. Transl.)].

    Google Scholar 

  14. A. G. Lee,J. Organometal. Chem, 1970,22, 237

    Google Scholar 

  15. A. I. Idelevich, I. F. Gun'kin, M. N. Rahlevskaya, and K. P. Butin,Metalloorg. Khim., 1990,3, 598 [J. Organometal. Chem. USSR, 1990,3 (Engl. Transl.)].

    Google Scholar 

  16. Yu. V. Karyakin and I. I. Angelov,Chistye Khimichexkiye Veshchestva [Pure Chemical Substances], Khimiya, Moscow, 1974, 230–231 (in Russian).

    Google Scholar 

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Authors and Affiliations

  1. Politechnical Institute, 410016, Saratov, Russian Federation

    I. F. Gun'kin

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  1. I. F. Gun'kin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1970–1973, November, 1993.

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Gun'kin, I.F. Organothallium compounds. Mechanistic study of the disproportionation reaction of organothallium compounds with copper in acetonitrile. Russ Chem Bull 42, 1887–1890 (1993). https://doi.org/10.1007/BF00699010

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  • DOI: https://doi.org/10.1007/BF00699010

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