Abstract
Diazotization of aminofurazans (1) and 4-aminofuroxans (2) with nitrosylsulfuric acid in a mixture of conc. H2SO4 and H3PO4 has been studied and offered as a general method for preparing furazanyl- (3) and furoxanyldiazonium (4) salts. It has been shown that reactions with the retention of the N-N-group (azo coupling, formation of triazenes and azides) are typical of salts3 and4, while elimination of the N2 molecule (Sandmeyer reaction, hydrolysis, reduction) is not typical.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1949–1953, November, 1993.
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Rakltin, O.A., Zalesova, O.A., Kulikov, A.S. et al. Synthesis and reactivity of furazanyl- and furoxanyldiazonium salts. Russ Chem Bull 42, 1865–1870 (1993). https://doi.org/10.1007/BF00699005
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DOI: https://doi.org/10.1007/BF00699005