Abstract
The title silanethione reacts with phosphorus ylides under conditions of kinetic control to give betaines containing a linear\(\begin{array}{*{20}c} \backslash \\ --- \\ / \\ \end{array} P^ + ---\begin{array}{*{20}c} | \\ C \\ | \\ \end{array} ---Si---S^ -\) fragment. Under conditions of thermodynamic control, the derivatives of phosphonium 1-silaacenaphthene-1-thiolate are formed.
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References
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2140–2141, December, 1993.
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Borisova, I.V., Zemlyansky, N.N., Shestakova, A.K. et al. Reaction of 8-(dimethylamino)methyl-1-naphthyl phenyl silanethione with phosphorus ylides. Russ Chem Bull 42, 2053–2054 (1993). https://doi.org/10.1007/BF00698899
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DOI: https://doi.org/10.1007/BF00698899