Abstract
The structure of azimexone (3), the product of the reaction of 2-cyanoaziridine with acetone, was confirmed on the basis of1H and13C NMR spectra. The formation of this product is accounted for by the α-aziridinoalkylating action of an intermediate containing a good leaving iminoyloxy group. Similar reactions were observed for 1-chloromethylaziridine and a 1-aziridinylmethylammonium salt (6), but not for 1-methoxymethylaziridine (7) and 1-aziridinemethanol.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2136–2139, December, 1993.
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Koehler, K.F., Zaddach, H., Kadorkina, G.K. et al. Structure of products of the reaction of 2-cyanoaziridine with carbonyl compounds. Russ Chem Bull 42, 2049–2052 (1993). https://doi.org/10.1007/BF00698898
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DOI: https://doi.org/10.1007/BF00698898