Skip to main content
Log in

Bromination of polyfluorinated α,β-enones

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Polyfluoroalkyl-α,β-enones readily add Br2 to give α,ß-dibromoketones. The latter are readily and regioselectively dehydrobrominated to α-bromo-α,β-enones on treatment with K2CO3 or NEt3

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. N. K. Kochetkov,Usp. Khim., 1955,24, 32 [Russ. Chem. Rev., 1955,24 (Engl. Transl.)].

    Google Scholar 

  2. N. H. Cromwell and R. P. Canoy,J. Am. Chem. Soc., 1958,80, 5524.

    Google Scholar 

  3. J. M. Adoff and M. C. Cabaleiro,An. Asoc. Quim. Argent., 1974,62, 233.

    Google Scholar 

  4. M. C. Cabaleiro and A. B. Chopa,J. Chem. Soc., Perkin Trans. 2, 1074,62, 452.

    Google Scholar 

  5. US Pat. 2787573;Chem. Abstrs., 1957,51, 9999d.

  6. S. Dershowtz and S. Proskauer,J. Org. Chem., 1961,26, 3595.

    Google Scholar 

  7. A. Lovelace, D. A. Rausch, and W. Postelnek,Aliphatic Fluoro-Containing Compounds, Reinhold, New York, 1958.

    Google Scholar 

  8. R. R. Latypov, V. D. Belogai, and K. I. Pashkevich,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 123 [Bull. Acad. Sci. USSR, Div. Chem. Sci, 1986,35, 108 (Engl. Transl.)].

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2134–2136, December, 1993.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Filyakova, V.I., Latypov, R.R. & Pashkevich, K.I. Bromination of polyfluorinated α,β-enones. Russ Chem Bull 42, 2047–2048 (1993). https://doi.org/10.1007/BF00698897

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00698897

Key words

Navigation