Abstract
Tributyl- and tribenzylbismuth react with aliphatic alcohols in the presence of copper diacetate to give dialkyl ethers, with yields of 0.10–0.25 moles per mole of the organobismuth compound.
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A. V. Gushchin, T. G. Brilkina, and V. A. Dodonov,Zh. Obshch. Khim., 1985,55, 2630 [J. Gen. Chem. USSR, 1985,55 (Engl. Transl.)].
V. A. Dodonov, A. V. Gushchin, T. G. Brilkina, and L. V. Muratova,Zh. Obshch. Khim., 1986,56, 2714 [J. Gen. Chem. USSR, 1986,56 (Engl. Transl.)].
V. A. Dodonov and A. V. Gushchin,Metalloorg. Khim., 1990,3, 112 [Organomet. Chem. USSR, 1990,3 (Engl. Transl.)].
V. A. Dodonov, T. I. Starostina, and V. V. Balukova,Zh. Obshch. Khim., 1992,62, 1 [J. Gen. Chem. USSR, 1992,62 (Engl. Transl.)].
N. A. Clinton and J. K. Kochi,J. Organomet. Chem., 1972,42, 241.
Metody elementoorganicheskoi khimii. Podgruppa medi, skandiya, titana, vanadiya, khroma, margantsa. Lantanoidy i aktinoidy [Methods of Organometallic Chemistry. Copper, Scandium, Titanium, Vanadium, Chromium, and Manganese Subgroup. Lanthanides and Actinides], Eds. A. N. Nesmeyanov and K. A. Kocheshkov, Nauka, Moscow, 1974 (in Russian).
K. A. Kocheshkov, A. P. Skoldinov, and N. N. Zemlyanskii,Metody elementoorganicheskoi khimii. Sur'ma, vismut [Methods of Organometallic Chemistry. Antimony and Bismuth], Nauka, Moscow, 1976 (in Russian).
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2109–2111, December, 1993.
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Dodonov, V.A., Starostina, T.I., Belukhina, E.V. et al. Tributyl- or tribenzylbismuth-copper diacetate system as an alkylating reagent for alcohols. Russ Chem Bull 42, 2023–2025 (1993). https://doi.org/10.1007/BF00698889
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DOI: https://doi.org/10.1007/BF00698889