Abstract
The reaction of methylmagnesium iodide with di(n-butyl)cyanamide results in dibutylamine, dibutylisopropylamine, and acetonitrile, while the reaction with di(n-butyl)nitrosamine affords acetaldehyde dibutylhydrazone. Formaldehyde, acetone, and 2-butanone dibutylhydrazones, as well as acetaldehyde butyl(1-methylbutyl)hydrazone, 2-butanone butyl(1-methylbutyl)hydrazone, 1,1-dibutyl-2,2-dimethylhydrazine, and 1,1-dibutyl-2-ethyl-2-methylhydrazine were also identified in minor amounts. Di(n-butyl)nitramine reacts with methylmagnesium iodide to give di(n-butyl)nitrosamine.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2078–2081, December, 1993.
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Polivin, Y.N., Karakhanov, R.A., Kelarev, V.I. et al. Reaction of methylmagnesium iodide with dibutylcyanamide and dibutylnitrosamine. Russ Chem Bull 42, 1991–1994 (1993). https://doi.org/10.1007/BF00698881
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DOI: https://doi.org/10.1007/BF00698881