Russian Chemical Bulletin

, Volume 42, Issue 3, pp 436–440 | Cite as

Activation of low-percentage Re-Al2O3 and Tc-Al2O3 catalysts for the dehydrogenation of paraffins

  • A. P. Barkova
  • O. V. Bragin
  • D. B. Furman
Physical Chemistry
  • 20 Downloads

Abstract

The activity and selectivity of low-percentage (0.1–1 mass. %) Re-Al2O3 and Tc-Al2O3 catalysts in the dehydrogenation ofn-dodecane is shown to increase in response to an increase in the temperature of their activation in hydrogen from 500°C to 900°C. The activities of such catalysts are comparable to those of analogous alumina-platinum systems, while the selectivity of the former catalysts inn-monoolefin production is higher than that of the latter.

Key words

dehydrogenation n-dodecane monoolefin rhenium technetium 

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Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • A. P. Barkova
    • 1
  • O. V. Bragin
    • 1
  • D. B. Furman
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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