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Homolytic addition of benzylidene bromide to trimethylvinylsilane and 1-hexene

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Abstract

Benzylidene bromide reacts with unsaturated compounds CH2=CHR (R = Bu, SiMe3) in the presence of benzoyl peroxide to give PhCHBrCH2CHRBr adducts.

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References

  1. T. T. Vasil'eva, S. I. Gapusenko, S. V. Vitt, and A. B. Terent'ev,Izv. Akad. Nauk, Ser. Khim., 1992, 2347 [Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992,41, 1841 (Engl. Transl.)].

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  2. S. E. Bottle, W. K. Busfield, and I. D. Jenkins,J. Chem. Soc., Perkin Trans. 2, 1992, 2145.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    S. I. Gapusenko, T. T. Vasil'eva, E. I. Misov & A. B. Terent'ev

Authors
  1. S. I. Gapusenko
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  2. T. T. Vasil'eva
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  3. E. I. Misov
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  4. A. B. Terent'ev
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1337–1338, July, 1994.

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Gapusenko, S.I., Vasil'eva, T.T., Misov, E.I. et al. Homolytic addition of benzylidene bromide to trimethylvinylsilane and 1-hexene. Russ Chem Bull 43, 1277–1278 (1994). https://doi.org/10.1007/BF00698261

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  • DOI: https://doi.org/10.1007/BF00698261

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