Russian Chemical Bulletin

, Volume 43, Issue 7, pp 1275–1277 | Cite as

Auration of ruthenocene: synthesis and molecular structure of mono- and diaurated derivatives

  • M. N. Nefedova
  • I. A. Mamed'yarova
  • V. I. Sokolov
  • E. I. Smyslova
  • L. G. Kuz'mina
  • K. I. Grandberg
Brief Communications

Abstract

Ruthenocene, like ferrocene, reacts with (Ph3PAu)3O+BF4 to afford agem-diaurated derivative CpRuC5H4(AuPPh3)2+BF4, which is converted into CpRuC5H4AuPPh3 when treated with PPh3. X-ray structural analysis revealed substantial Ru-Au interaction in the diaurated derivative.

Key words

ruthenocene gold-containing oxonium salt auration 

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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • M. N. Nefedova
    • 1
  • I. A. Mamed'yarova
    • 1
  • V. I. Sokolov
    • 1
  • E. I. Smyslova
    • 1
  • L. G. Kuz'mina
    • 1
  • K. I. Grandberg
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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