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Synthesis and structure of [(DMSO)2H][OsNO(DMSO)Cl4]

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Abstract

A new complex of dimethyl sulfoxide nitrosoosmium [(DMSO)2H][OsNO(DMSO)Cl4] has been prepared by reacting H2[OsNOCl5] with DMSO in acetone. Its structure has been established by IR spectroscopy and X-ray structural analysis.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571, Moscow, Russian Federation

    O. V. Rudnitskaya, T. M. Buslaeva, N. A. Koteneva & A. I. Stash

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  1. O. V. Rudnitskaya
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  2. T. M. Buslaeva
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  3. N. A. Koteneva
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  4. A. I. Stash
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1333–1334, July, 1994.

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Rudnitskaya, O.V., Buslaeva, T.M., Koteneva, N.A. et al. Synthesis and structure of [(DMSO)2H][OsNO(DMSO)Cl4]. Russ Chem Bull 43, 1273–1274 (1994). https://doi.org/10.1007/BF00698259

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  • DOI: https://doi.org/10.1007/BF00698259

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