Abstract
The reaction between (Et3Ge)2Cd and TiCl4 in the presence of α,α′-bipyridyl afforded a compound with a Ge-Cd-Ti group. This compound was characterized by IR and ESR spectroscopy. Thermal decomposition of this compound at 130 and 160 °C and its interaction with gaseous HCl were studied. A novel complex, (Et3Ge)2Cd · bpy, was obtained as a by-product of the reaction, and some its physicochemical characteristics were determined. Based on the experimental results, a scheme for the interaction of (Et3Ge)2Cd with TiCl4 has been suggested.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1305–1307, July, 1994.
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Lomakova, I.V., Patrikeeva, N.B., Domrachev, G.A. et al. Investigation of the reaction of bis(triethylgermyl)cadmium with titanium tetrachloride. Russ Chem Bull 43, 1242–1244 (1994). https://doi.org/10.1007/BF00698253
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DOI: https://doi.org/10.1007/BF00698253