Russian Chemical Bulletin

, Volume 43, Issue 7, pp 1231–1238 | Cite as

Synthesis of new organothiophosphorus insectoacaricides containingN-acylated amino acid fragments

  • A. E. Shipov
  • G. K. Genkina
  • G. V. Zhdanova
  • P. V. Petrovskii
  • S. A. Roslavtseva
  • I. N. Sazonova
  • O. V. Sundukov
  • L. S. Golovkina
  • R. I. Volkova
  • Yu. S. Kagan
  • E. A. Ershova
  • T. A. Mastryukova
  • M. I. Kabachnik
Organic Chemistry
  • 41 Downloads

Abstract

Methods for the synthesis ofO-alkylS-(N-acyl-N-alkoxycarbonylalkyl)aminomethyl (methyl)thio- and -dithiophosphonates based on the reaction between alkaline-metal salts ofO-alkyl (methyl)thio- and -dithiophosphonates and N-alkoxycarbonyl-N-chloromethylglycine or -β-alanine esters and by treatment ofO-alkyl (methyl)dithiophosphonoates andN-acylated amino acids or their esters with paraform in the presence of HCl were developed. The compounds obtained exhibit high insectoacaricide activity and selectivity.

Key words

(methyl)thiophosphonates (methyl)dithiophosphonates thiophosphorylated derivatives of amino acids insectoacaricides 

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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • A. E. Shipov
    • 1
  • G. K. Genkina
    • 1
  • G. V. Zhdanova
    • 1
  • P. V. Petrovskii
    • 1
  • S. A. Roslavtseva
    • 1
  • I. N. Sazonova
    • 1
  • O. V. Sundukov
    • 1
  • L. S. Golovkina
    • 1
  • R. I. Volkova
    • 1
  • Yu. S. Kagan
    • 1
  • E. A. Ershova
    • 1
  • T. A. Mastryukova
    • 1
  • M. I. Kabachnik
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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