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Synthesis and properties of functional derivatives ofN′-phosphoryl- andN′-phosphonoyldiazeneN-oxides; molecular structure ofN-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-N′-[methoxy(phenyl)phosphoryl]diazeneN-oxide

  • Organic Chemistry
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Abstract

Methods for the synthesis of polyfunctionalN′-phosphoryl- andN′-phosphonoyldiazeneN-oxides containing hydroxyl, acetoxyl, and nitrate groups, and dibromoallyl and dibromopropyl fragments have been developed. The molecular structure ofN-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-N′-[methoxy(phenyl)phosphoryl)diazeneN-oxide was established by X-ray structural analysis.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    S. G. Zlotin, M. V. Sharashkina, Yu. A. Strelenko, O. A. Luk'yanov & M. O. Dekaprilevich

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    Yu. T. Struchkav

Authors
  1. S. G. Zlotin
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  2. M. V. Sharashkina
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  3. Yu. A. Strelenko
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  4. O. A. Luk'yanov
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  5. M. O. Dekaprilevich
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  6. Yu. T. Struchkav
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1284–1289, July, 1994.

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Zlotin, S.G., Sharashkina, M.V., Strelenko, Y.A. et al. Synthesis and properties of functional derivatives ofN′-phosphoryl- andN′-phosphonoyldiazeneN-oxides; molecular structure ofN-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-N′-[methoxy(phenyl)phosphoryl]diazeneN-oxide. Russ Chem Bull 43, 1220–1226 (1994). https://doi.org/10.1007/BF00698249

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  • DOI: https://doi.org/10.1007/BF00698249

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