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Russian Chemical Bulletin

, Volume 43, Issue 7, pp 1200–1202 | Cite as

Dinitramide and its salts

2. Dinitramide in Michael- and retro-Michael-type reactions
  • O. A. Luk'yanov
  • Yu. V. Konnova
  • T. A. Klimova
  • V. A. Tartakovsky
Organic Chemistry

Abstract

Dinitramide readily adds to acrolein, methyl vinyl ketone, and phenyl vinyl ketone, but not to acrylonitrile or methyl acrylate. Treatment of dinitro compounds (O2N)2NCH2CH2COR (R = H, Me, Ph, OMe) with bases results in dinitramide salts in 66–83 % yields.

Key words

dinitramide salts N,N-dinitramines Michael- and retro-Michael-type reactions 

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References

  1. 1.
    O. A. Luk'yanov, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 94 [Russ. Chem. Bull., 1994,43, 89 (Engl. Transl.)].Google Scholar
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    O. A. Luk'yanov, V. P. Gorelik, O. S. Reshetova, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 1261 [Russ. Chem. Bull., 1994,43, 1197 (Engl. Transl.)].Google Scholar
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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • O. A. Luk'yanov
    • 1
  • Yu. V. Konnova
    • 1
  • T. A. Klimova
    • 1
  • V. A. Tartakovsky
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesRussian Federation

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