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Ethyl 3,3-diamino-2-(2-p-tolylpyrimidin-4-yl)acrylate, a new representative of hetarylketene aminals

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A new representative of hetarylketene aminals, ethyl 3,3-diamino-2-(2-p-tolylpyrimidin-4-yl)acrylate, was synthesized by the reaction ofp-toluamidine with the condensation product of dimethylformamide dimethyl acetal and the difluoroboron chelate of acetyl(ethoxycarbonyl)ketene (N-benzoyl)aminal. This synthesis is an example of pyrimidine ring assembly using the methodology based on transformations of chelate complexes.

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References

  1. V. A. Dorokhov, M. F. Gordeev, Z. K. Demyanets, and V. S. Bogdanov,Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 1683 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987,36, 1564 (Engl. Transl.)].

    Google Scholar 

  2. V. A. Dorokhov, M. F. Gordeev, Z. K. Demyanets, M. N. Bochkareva, and V. S. Bogdanov,Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 1806 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989,38, 1654 (Engl. Transl.)].

    Google Scholar 

  3. V. A. Dorokhov, M. F. Gordeev, A. V. Komkov, and V. S. Bogdanov,Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 401 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990,39, 340 (Engl. Transl.)].

    Google Scholar 

  4. V. A. Dorokhov and M. F. Gordeev,Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 1211 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989,38, 1104 (Engl. Transl.)].

  5. V. A. Dorokhov and M. F. Gordeev,Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 2874 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989,38, 2638 (Engl. Transl.)].

  6. V. A. Dorokhov, M. F. Gordeev, and M. A. Present,Izv. Akad. Nauk SSSR, Ser. Khim., 1991, 525 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991,40, 457 (Engl. Transl.)].

    Google Scholar 

  7. V. A. Dorokhov and M. A. Present,Izv. Akad. Nauk, Ser. Khim., 1993, 1504 [Russ. Chem. Bull., 1993,42, 1442 (Engl. Transl.)].

    Google Scholar 

  8. V. A. Dorokhov and M. A. Present,Izv. Akad. Nauk, Ser. Khim., 1994, 888 [Russ. Chem. Bull., 1994,43, 832 (Engl. Transl.)].

    Google Scholar 

  9. V. L. Gein, S. G. Pitirimova, Yu. S. Andreychikov, M. F. Gordeev, V. S. Bogdanov, and V. A. Dorokhov,Izv. Akad. Nauk, Ser. Khim., 1992, 1225 [Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992,41, 968 (Engl. Transl.)].

  10. H. D. Hinton and J. A. Nieuwland,J. Am. Chem. Soc., 1932,54, 2017.

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    V. A. Dorokhov, M. A. Present & V. S. Bogdanov

Authors
  1. V. A. Dorokhov
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  2. M. A. Present
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  3. V. S. Bogdanov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1638–1640, September, 1994.

This research was partially supported by the International Science Foundation (Grant No. M5QOOO).

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Dorokhov, V.A., Present, M.A. & Bogdanov, V.S. Ethyl 3,3-diamino-2-(2-p-tolylpyrimidin-4-yl)acrylate, a new representative of hetarylketene aminals. Russ Chem Bull 43, 1550–1552 (1994). https://doi.org/10.1007/BF00697147

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  • DOI: https://doi.org/10.1007/BF00697147

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