Skip to main content
SpringerLink
Log in

Vibrational spectra and structure of zirconium and hafnium cyclopentadienyl hydrides

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Raman and IR spectra (4000-50 cm−1) of solid cyclopentadienyl zirconium and hafnium hydrides Cp2MH2, Cp2MD2, Cp2Zr(H)X, and Cp2Zr(D)X (Cp = η5-C5H5; M = Zr, Hf; X = Cl, Br) have been studied. The vibrational modes of MH groups, Cp-rings, and metal-ligand bonds are discussed and the band assignments are proposed. In the solid state, these complexes form polymers with linear hydride bridges of the M-H-M type. The force constants of the M-H and M-Cp bonds increase on going from Zr to Hf.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. B. Jones and J. L. Petersen,Inorg. Chem., 1981,20, 2889.

    Google Scholar 

  2. W. L. Jarrett, R. D. Farlee, and L. G. Butler,Inorg. Chem., 1987,26, 1381.

    Google Scholar 

  3. B. V. Lokshin, Z. S. Klemenkova, M. G. Ezernitzkaya, L. I. Strunkina, and E. M. Brainina,J. Organomet. Chem., 1982,235, 69.

    Google Scholar 

  4. E. M. Brainina, L. I. Strunkina, B. V. Lokshin, and M. G. Ezernitzkaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 447 (in Russian).

  5. P. S. Wailes and H. Weigold,J. Organomet. Chem., 1970,24, 405.

    Google Scholar 

  6. J. E. Bercaw,Adv. Chem. Ser., 1978,167, 136.

    Google Scholar 

  7. P. T. Wolczanski and J. E. Bercaw,Organometallics, 1982,1, 793.

    Google Scholar 

  8. J. M. Manriquez, D. R. Mc Allister, R. D. Sanner, and J. E. Bercaw,J. Am. Chem. Soc., 1978,100, 2716.

    Google Scholar 

  9. D. G. Bickley, N. Hao, P. Bougeard, B. G. Sayer, R. C. Burns, and M. J. Mc Glinchey,J. Organomet. Chem., 1983,246, 257.

    Google Scholar 

  10. L. I. Strunkina, M. Kh. Minacheva, Z. S. Klemenkova, and B. V. Lokshin,Metalloorg. Khim., 1991,4, 819 [Organomet. Chem. USSR, 1991,4, 398 (Engl. Transl.)].

    Google Scholar 

  11. L. I. Strunkina, M. Kh. Minacheva, Z. S. Klemenkova, L. V. Vinogradova, and B. V. Lokshin,Metalloorg. Khim., 1989,2, 1054 [Organomet. Chem. USSR, 1989,2 (Engl. Transl.)].

    Google Scholar 

  12. L. I. Strunkina, Z. S. Klemenkova, B. V. Lokshin, and E. M. Brainina,Metalloorg. Khim., 1988,1, 389 [Organomet. Chem. USSR, 1988,1 (Engl. Transl.)].

    Google Scholar 

  13. L. I. Strunkina, M. Kh. Minacheva, Z. S. Klemenkova, and B. V. Lokshin,Metalloorg. Khim., 1989,2, 1196 [Organomet. Chem. USSR, 1989,2, 635 (Engl. Transl.)].

    Google Scholar 

  14. E. M. Brainina, L. I. Strunkina, N. A. Kuz'mina, and E. M. Grechkina,Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 228 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985,34, 216 (Engl. Transl.)].

    Google Scholar 

  15. S. V. Trepalin and B. P. Novikov,Zh. Prikl. Spektrosc., 1980,33, 545 [(J. Appl. Spectrosc. USSR, 1980,33 (Engl. Transl.)].

    Google Scholar 

  16. G. A. Tolstikov, M. S. Mishtakov, and F. A. Valeev,Izv. Akad. Nauk SSSR, Ser. Khim., 1979, 2576 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1979,28, 2392 (Engl. Transl.)].

    Google Scholar 

  17. E. Maslovsky, Jr.,Vibrational Spectra of Organometallic Compounds, J. Wiley, New York, 1977.

    Google Scholar 

  18. H. Weigold, A. P. Bell, and R. I. Willing,J. Organomet. Chem., 1974,73, C23.

    Google Scholar 

  19. V. T. Aleksanyan and B. V. Lokshin,Kolebatel'nye spektry π-kompleksov perekhodnykh metallov, Ser. Usp. nauki i tekhniki [Vibrational Spectra of Transition Metal π-Complexes, Div. Adv. Sci. Techn.], VINITI, Moscow, 1976 (in Russian).

    Google Scholar 

  20. E. Maslovsky and K. Nakamoto,Appl. Spectrosc., 1981,25, 187.

    Google Scholar 

  21. E. Samuel, R. Ferner, and M. Bigorgne,Inorg. Chem., 1973,12, 881.

    Google Scholar 

  22. P. M. Duce, B. M. Kingston, M. F. Lappert, R. C. Srivastava, M. J. Frazer, and W. E. Newton,J. Chem. Soc. A, 1969, 2814.

    Google Scholar 

  23. H. A. Martin, M. van Gorkom, and R. O. De Jongh,J. Organomet. Chem., 1972,36, 93.

    Google Scholar 

  24. Z. S. Klemenkova, B. V. Lokshin, M. Kh. Minacheva, and O. A. Mikhailova,Metalloorg. Khim., 1990,3, 144 [Organomet. Chem. USSR, 1990,3, 78 (Engl. Transl.)].

    Google Scholar 

  25. B. V. Lokshin, Z. S. Klemenkova, M. Kh. Minacheva, G. I. Timofeeva, and E. M. Brainina,Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 2599 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985,34, 2409 (Engl. Transl.)].

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul Vavilova, 117813, Moscow, Russian Federation

    Z. S. Klemenkova, B. V. Lokshin, L. I. Strunkina & M. Kh. Minacheva

Authors
  1. Z. S. Klemenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. V. Lokshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. I. Strunkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Kh. Minacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1604–1609, September, 1994.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Klemenkova, Z.S., Lokshin, B.V., Strunkina, L.I. et al. Vibrational spectra and structure of zirconium and hafnium cyclopentadienyl hydrides. Russ Chem Bull 43, 1516–1521 (1994). https://doi.org/10.1007/BF00697139

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00697139

Key words

Search

Navigation