Abstract
The spectral and activation parameters of chemiluminescence in the thermal decay of 1,2-dioxetane based on adamantylideneadamantane in acetonitrile in the presence of TbIII, EuIII, PrIII, CeIII, and GdIII perchlorates and UO2(NO3)2 have been studied. Two types of catalysis by metals, luminescent and nonluminescent, can be distinguished in the framework of one mechanism of dioxetane decay initiated by metal-peroxide complex formation. The mode of catalysis depends both on the presence of suitable energy levels in the metal ion to which the intracomplex transfer of excitation from the3n,π*-state of the ketone that appears in the decay of dioxetane in a catalytic complex can occur and on the ratio of the quantum yields of luminescence of the ketone and the metal ion that is the catalytic activator of luminescence.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
W. Adam, inChemistry of Functional Groups, Peroxides, Ed. S. Patai, Wiley, New York, 1983, 829.
G. L. Sharipov, V. P. Kazakov, and G. A. Tolstikov, inKhimiya i lyuminestsentsiya 1,2-dioksetanov [Chemistry and Luminescence of 1,2-Dioxetanes], Nauka, Moscow, 1990, 227 (in Russian).
F. McCapra and D. Watmore,Tetrahedron Lett., 1982,23, 5225.
S. S. Ostakhov, G. L. Sharipov, A. I. Voloshin, V. P. Kazakov, and G. A. Tolstikov,Dokl. Akad. Nauk SSSR, 1986,287, 1165 [Dokl. Chem., 1986,287 (Engl. Transl.)].
S. S. Ostakhov, G. L. Sharipov, V. P. Kazakov, and G. A. Tolstikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 1745 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990,39, 1581 (Engl. Transl.)].
G. L. Sharipov, A. I. Voloshin, V. P. Kazakov, and G. A. Tolstikov,Dokl. Akad. Nauk SSSR, 1990,315, 425 [Dokl. Chem., 1990,315 (Engl. Transl.)].
G. B. Schuster, N. J. Turro, H.-C. Steinmetzer, A. P. Schaap, G. Faler, W. Adam, and J. C. Liu,J. Am. Chem. Soc., 1975,97, 7110.
E. W. Meijer and H. Wynberg,J. Chem. Educ., 1982,59, 1071.
G. A. Tolstikov, G. L. Sharipov, A. I. Voloshin, S. S. Ostakhov, and V. P. Kazakov,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 787 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986,35, 715 (Engl. Transl.)].
R. G. Bulgakov, B. A. Tishin, V. P. Vlad, G. Ya. Maistrenko, S. S. Ostakhov, G. A. Tolstikov, and V. P. Kazakov,Khim. Vys. Energ., 1989,23, 250 [High Energy Chem., 1989,23 (Engl. Transl.)].
V. P. Kazakov, G. L. Sharipov, A. I. Voloshin, and G. A. Tolstikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 2187 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990,39, 1997 (Engl. Transl.)].
V. L. Ermolaev, E. N. Bodunov, E. B. Sveshnikova, and T. A. Shakhverdov, inBezyzluchatel'nyi perenos elektronnogo vozbuzhdeniya [Nonradiative Transfer of Electronic Excitation], Nauka, Leningrad, 1977, 216 (in Russian).
H. Nakamura and T. Goto,Photochem. Photobiol., 1979,30, 27.
D. R. Charney, J. C. Dalton, R. R. Hautala, J. J. Snyder, and N. J. Turro,J. Am. Chem. Soc., 1974,96, 1407.
A. V. Yankelevich, I. V. Khudyakov, and A. L. Buchachenko,Khim. Fiz., 1988,7, 734 [Chem. Phys. USSR, 1988,7 (Engl. Transl.)].
V. P. Kazakov and G. L. Sharipov, inRadiolyuminestsentsiya vodnykh rastvorov [Radioluminescence of Aqueous Solutions], Nauka, Moscow, 1986, 70 (in Russian).
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1588–1592, September, 1994.
The authors are grateful to S. S. Ostakhov for measuring the spectra and the duration of photoluminescence of terbium in dioxetane solutions and for participation in discussions of the results.
Rights and permissions
About this article
Cite this article
Sharipov, G.L., Ableeva, N.S. & Kukovinets, A.G. Chemiluminescence initiated by complex formation in solutions of 1,2-dioxetane and lanthanide perchlorates. Russ Chem Bull 43, 1500–1504 (1994). https://doi.org/10.1007/BF00697135
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00697135