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1H,13C NMR spectral data for α-, β-, and γ-lewisites and identification ofcis, trans, trans-γ-lewisite as a new isomer

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Abstract

The1H and13C NMR spectral parameters of α-, β-, and y-lewisites1–5 were obtained and a new isomer,cis,trans,trans-γ-lewisite5, was isolated and identified on the basis of chemical shifts, relative intensities of the signals, and the intra-chain (3 J hh ,3 J ch ) and interchain (3 J casch ) coupling constants.

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Authors and Affiliations

  1. Gesellschaft fur Beseitigung von Kampfmitteln, Kampfstoffen, Kampfstoffmunition, Dr. Koehler GmbH. Barbarahof, kreutzen 17, D-03042, Munster, Germany

    K. F. Koehler & H. Zaddach

  2. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    A. D. Kuntsevich, V. N. Voznesenskii, I. I. Chervin & R. G. Kostyanovsky

Authors
  1. K. F. Koehler
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  2. H. Zaddach
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  3. A. D. Kuntsevich
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  4. V. N. Voznesenskii
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  5. I. I. Chervin
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  6. R. G. Kostyanovsky
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1833–1835, October, 1993.

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Koehler, K.F., Zaddach, H., Kuntsevich, A.D. et al. 1H,13C NMR spectral data for α-, β-, and γ-lewisites and identification ofcis, trans, trans-γ-lewisite as a new isomer. Russ Chem Bull 42, 1757–1759 (1993). https://doi.org/10.1007/BF00697061

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  • DOI: https://doi.org/10.1007/BF00697061

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