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Cr, Co, and Mn arene π-complexes based on diphenyl- and triphenylmethane

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Abstract

The interaction of Ph2CH2 and Ph3CH with Cr(CO)6, Co2(CO)8, and Mn(CO)5BF4 leads to mononuclear LCr(CO)3, LCo4(CO)9, and [LMn(CO)3]BF4 π-arene complexes. Similarly, LCr(CO)3Co4(CO)9 and [LCr(CO)3Mn(CO)3]BF4 heteroaromatic derivatives are obtained from LCr(CO)3 complexes, whereas LCo4(CO)9 complexes afford L[Co4(CO)9]2 bicluster derivatives.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    V. S. Kaganovick & M. L. Rybinskaya

Authors
  1. V. S. Kaganovick
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  2. M. L. Rybinskaya
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1809–1812, October, 1993.

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Kaganovick, V.S., Rybinskaya, M.L. Cr, Co, and Mn arene π-complexes based on diphenyl- and triphenylmethane. Russ Chem Bull 42, 1734–1737 (1993). https://doi.org/10.1007/BF00697053

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