Abstract
The carbonylation of the (S)-enantiomer of the palladated derivative of dimethyl-aminomethylferrocene in the presence of 1,2-bis(hydroxymethyl)cymantrene affords a product containing a chiral plane predominantly of the (R)-configuration. The extent of asymmetric induction amounts to 30–35 %.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1799–1802, October, 1993.
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Troitskaya, L.L., Bulygina, L.A. & Sokolov, V.I. Diastereoselectivity in the induction of planar chirality in prochiral cymantrenes. Russ Chem Bull 42, 1724–1726 (1993). https://doi.org/10.1007/BF00697050
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DOI: https://doi.org/10.1007/BF00697050