Abstract
The formation of trichlorogermyl-substituted amides, lactams, and imides occurs when 2Et2O·HGeCl3 is condensed with compounds possessing the -NCH2Cl fragment and equally well when HGeCl3 interacts with compounds containing -NCH2OH and-NCH2OSiMe3 groups. In some cases, the use of the latter is more advantageous from the preparative point of view. In compounds thus obtained, the germanium is five-coordinate due to the coordination
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Deceased August 13, 1993.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1793–1799, October, 1993.
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Gar, T.K., Dombrova, O.A., Ivashchenko, D.A. et al. Synthesis, structures and properties ofN-(trihalogermylmethyl)-substituted amides, lactams and imides, the derivatives of the five-coordinate germanium. Russ Chem Bull 42, 1717–1723 (1993). https://doi.org/10.1007/BF00697049
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DOI: https://doi.org/10.1007/BF00697049